Transport properties of MF-4SK perfluorinated membranes modified with zirconium hydrogen phosphate

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Physicochemical and transport characteristics of cast and extruded MF-4SK perfluorinated membranes modified with zirconium hydrogen phosphate in an amount of 3–10% are studied. The inorganic phase is formed in the membrane volume by pore-filling method. The effect of zirconium hydrogen phosphate content on the exchange capacity, water content, diffusion permeability for electrolyte solution, hydrogen gas permeability and conductivity at limited humidity of the MF-4SK membrane, as well as the efficiency of its use in a proton exchange membrane fuel cell are studied. A non-monotonic change in transport characteristics from the dopant content is shown. The lowest diffusion permeability and maximum electrical conductivity at low humidity possesses the membrane containing 6% zirconium hydrogen phosphate. The maximum specific power of the proton-exchange membrane fuel cell with modified membranes as a polymer electrolyte is 17% higher compared to the original MF-4SK. This result is caused by lower ohmic resistance and kinetic limitations of membrane-electrode assembly with modified samples compared to the non-modified membrane, revealed on the basis of an analysis of its impedance spectra.

Sobre autores

I. Falina

Kuban State University

Autor responsável pela correspondência
Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

E. Meshcheryakova

Kuban State University

Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

K. Lyapishev

Kuban State University

Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

K. Demidenko

Kuban State University

Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

E. Titskaya

Kuban State University

Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

S. Timofeev

OAO “Plastpolymer”

Email: irina_falina@mail.ru
Rússia, 32 Polyustrovsky ave., St. Petersburg, 195197

N. Kononenko

Kuban State University

Email: irina_falina@mail.ru
Rússia, 149 Stavropol Street, Krasnodar, 350040

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