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EFFECTIVE SYNTHESIS OF OPTICALLY PURE MONO- AND BINUCULAR MACROCYCLIC POLYLACTONES FROM CASTOR OIL AND SEBACIC ACID
- Authors: Ishmuratov G.Y.1, Medvedeva N.I.1, Saitov K.M.1, Yakovleva M.P.1, Nazarov I.S.1, Tolstikov A.G.1
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Affiliations:
- Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
- Issue: Vol 513, No 1 (2023)
- Pages: 5-10
- Section: CHEMISTRY
- URL: https://rjmseer.com/2686-9535/article/view/651924
- DOI: https://doi.org/10.31857/S2686953522600738
- EDN: https://elibrary.ru/OCEWWO
- ID: 651924
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Abstract
An effective synthesis of optically pure macrocyclic mono- and dinuclearpolylactones is proposed, based on the condensation of a natural triol – castor oil with sebacic acid dichloride, taken in ratios 1 : 1 or 1 : 2, in boiling carbon tetrachloride in the presence of triethylamine and the catalyst N,N-dimethylaminopyridine.
About the authors
G. Yu. Ishmuratov
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
N. I. Medvedeva
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
K. M. Saitov
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
M. P. Yakovleva
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Author for correspondence.
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
I. S. Nazarov
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
A. G. Tolstikov
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences
Email: insect@anrb.ru
Russian Federation, 450054, Ufa
References
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