Email this article 
SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS OF HIGH-ENTROPY CARBIDES IN THE REGIME OF A GASLESS THERMAL EXPLOSION
- Authors: Vergunova Y.S.1, Vadchenko S.G.1, Kovalev I.D.1, Kovalev D.Y.1, Rogachev A.S.1, Alymov M.I.1
-
Affiliations:
- Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
- Issue: Vol 513, No 1 (2023)
- Pages: 131-134
- Section: PHYSICAL CHEMISTRY
- URL: https://rjmseer.com/2686-9535/article/view/651942
- DOI: https://doi.org/10.31857/S268695352360023X
- EDN: https://elibrary.ru/BJHJQF
- ID: 651942
Cite item
Open Access
Access granted
Subscription Access
Abstract
High-entropy carbides are a new class of inorganic compounds promising for a wide range of applications. The paper presents a new concept for the synthesis of powders of high-entropy carbides by the method of self-propagating high-temperature synthesis (SHS) in the gasless thermal explosion mode from previously mechanically synthesized and structured reaction mixtures. For the first time, high-entropy carbides TaTiNbVWC5 and TaNbVMoWC5 were obtained by this method, their crystal structure was determined, which was compared with similar compositions obtained by sintering.
About the authors
Yu. S. Vergunova
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
S. G. Vadchenko
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Author for correspondence.
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
I. D. Kovalev
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
D. Yu. Kovalev
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
A. S. Rogachev
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
M. I. Alymov
Merzhanov Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)
Email: vadchenko@ism.ac.ru
Russian Federation, 142432, Moscow Region, Chernogolovka
References
- Akrami S., Edalati P., Fuji M., Edalati K. // Mat. Sci. Eng. R: Rep. 2021. V. 146. 100644. https://doi.org/10.1016/j.mser.2021.100644
- Harrington T. J., Gild J., Sarker P., Toher C., Rost C.M., Dippo O.F., McElfresh C., Kaufmann K., Marin E., Borowski L., Hopkins P.E., Luo J., Curtarolo S., Brenner D.W., Vecchio K.S. // Acta Mater. 2019. V. 166. P. 271–280. https://doi.org/10.1016/j.actamat.2018.12.054
- Calzolari A., Oses C., Toher C., Esters M., Campilongo X., Stepanoff S.P., Wolfe D.E., Curtarolo S. // Nat. Commun. 2022. V. 13. 5993. https://doi.org/10.1038/s41467-022-33497-1
- Ye B., Wen T., Chu Y. // J. Am. Ceram. Soc. 2020. V. 103. P. 500–507. https://doi.org/10.1111/jace.16725
- Braic V., Vladescu A., Balaceanu M., Luculescu C.R., Braic M. // Surf. Coat. Technol. 2012. V. 211. P. 117–121. https://doi.org/10.1016/j.surfcoat.2011.09.033
- Braic V., Balaceanu M., Braic M., Vladescu A., Panseri S., Russo A. // J. Mech. Behav. Biomed. Mater. 2012. V. 10. P. 197–205. https://doi.org/10.1016/j.jmbbm.2012.02.020
- Pötschke J., Dahal M., Herrmann M., Vornberger A., Matthey B., Michaelis A. // J. Mater. Sci. 2021. V. 56. P. 11237–11247. https://doi.org/10.1007/s10853-021-06004-y
- Moskovskikh D.O., Vorotilo S., Sedegov A.S., Kuskov K.V., Bardasova K.V., Kiryukhantsev-Korneev P.V., Zhukovskyi M., Mukasyan A.S. // Ceram. Int. 2020. V. 46. № 11. P. 19008–19014. https://doi.org/10.1016/j.ceramint.2020.04.230
- Kovalev D.Yu., Kochetov N.A., Chuev I.I. // Ceram. Int. 2021. V. 47. P. 32626–32633. https://doi.org/10.1016/j.ceramint.2021.08.158
- Кочетов Н.А., Ковалев И.Д. // Неорг. матер. 2021. Т. 57. № 1. С. 10–15. https://doi.org/10.31857/S0002337X20120106
- Мержанов А.Г., Боровинская И.П. // Докл. АН СССР. 1972. Т. 204. № 2. С. 366–369.
- Tallarita G., Licheri R., Garroni S., Orrù R., Cao G. // Scr. Mater. 2019. V. 158. P. 100–104. https://doi.org/10.1016/j.scriptamat.2018.08.039
- Sedegov A.S., Bobojanov A.R., Vorotilo S., Kuskov K.V., Moscovskikh D.O. // IOP Conf. Ser.: Mater. Sci. Eng. 2021. V. 1014. 012049 (1–4). 10.1088/1757-899X/1014/1/012049' target='_blank'>https://doi.org/doi: 10.1088/1757-899X/1014/1/012049
- Vadchenko S.G., Boyarchenko O.D., Shkodich N.F., Rogachev A.S. // Int. J. Self-Propag. High-Temp. Synt. 2013. V. 22. № 1. P. 60–64. https://doi.org/10.3103/S1061386213010123
- Самсонов Г.В., Виницкий И.М. Тугоплавкие соединения. Справочник. 2‑е изд. М., “Металлургия”, 1976. 560 с.
