PREPARATION OF NEW HARD ELASTIC POLYMERIC MATERIAL BASED ON ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE

О. V. Аrzhakova; Аржакова О. В.; А. Yu. Yarusheva; Ярышева А. Ю.; A. I. Nazarov; Назаров А. И.; А. А. Dolgova; Долгова А. А.; A. L. Volynskii; Волынский А. Л.

doi:10.31857/S2686953522600623

PREPARATION OF NEW HARD ELASTIC POLYMERIC MATERIAL BASED ON ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE

Authors: Аrzhakova О.V.¹, Yarusheva А.Y.¹, Nazarov A.I.¹, Dolgova А.А.¹, Volynskii A.L.¹
Affiliations:
1. Lomonosov Moscow State University, Faculty of Chemistry
Issue: Vol 510, No 1 (2023)
Pages: 80-86
Section: PHYSICAL CHEMISTRY
URL: https://rjmseer.com/2686-9535/article/view/651979
DOI: https://doi.org/10.31857/S2686953522600623
EDN: https://elibrary.ru/OVTCHR
ID: 651979

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract

A novel approach for the preparation of hard elastic polymeric material based on ultra-high molecular weight polyethylene via the strategy of crazing of polymers has been proposed. This approach includes the process of deformation of the pristine films of ultra-high molecular weight polyethylene via environmental intercrystallite crazing mechanism and subsequent low-temperature spontaneous strain recovery upon stress relaxation. As a result, the material acquires new properties typical for hard elastic materials: restoration of the porous structure upon secondary loading in air up to ~20 vol. % with pore sizes in the nanometer range (up to 10 nm), high reversibility of deformation (50−85%), the effect of opening and closing pores upon cyclic loading. The mechanism of this phenomenon has been proposed and the areas of practical applications of such mechanoresponsive material have been indicated.

Keywords

ultra-high molecular weight polyethylene, crazing, mesoporous structure, hard elastic polymeric material, mechanoresponsive polymeric materials

References

Kurtz S.M. The UHMWPE handbook: Ultra-high molecular weight polyethylene in total joint replacemen. 1st edition. San Diego, CA, USA: Elsevier, 2004. 396 p.
Hussain M., Naqvi R.A., Abbas N.R., Khan S.M., Nawaz S., Hussain A., Zahra N., Khalid M.W. // Polymers. 2020. V. 12. № 2. P. 323. https://doi.org/10.3390/polym12020323
Ahmed D.S., El-Hiti G.A., Yousif E., Ali A.A., Hame-ed A.S. // J. Polym. Res. 2018. V. 25. P. 75. https://doi.org/10.1007/s10965-018-1474-x
Samad M.A., Sinha S.K. // Tribol. Let. 2010. V. 38. P. 301−311. https://doi.org/10.1007/s11249-010-9610-8
Salimon A.I., Statnik E.S., Zadorozhnyy M.Yu., Sena-tov F.S., Zherebtsov D.D., Safonov A.A., Korsunsky A.M. // Materials. 2019. V. 12. № 13. P. 2195. https://doi.org/10.3390/ma12132195
Submicron porous materials. Bettotti P. (Ed.). Springer, 2017. 346 p.
Sprague B.S. // J. Macromol. Sci., Part B. 1973. V. 8. P. 157–187. https://doi.org/10.1080/00222347308245798
Xie J.Y., Xu R.J., Lei C.H. // Chinese J. Polym. Sci. 2020. V. 38. № 12. P. 1325−1334. https://doi.org/10.1007/s10118-020-2432-8
Lin Y., Li X., Meng L., Chen X., Lv F., Zhang Q., Zhang R., Li L. // Macromolecules. 2018. V. 51. № 7. P. 2690−2705. https://doi.org/10.1021/acs.macromol.8b00255
Lin Y., Li X., Chen X., An M., Zhang Q., Wang D., Chen W., Sun L., Yin P., Meng L., Li L. // Polymer. 2019. V. 184. P. 121930. https://doi.org/10.1016/j.polymer.2019.121930
Okkelman I.A., Dolgova A.A., Banerjee S., Kerry J.P., Volynskii A., Arzhakova O.V., Papkovsky D.B. // ACS Appl. Mater. Interfaces. 2017. V. 9. № 15. P. 13587−13592. https://doi.org/10.1021/acsami.7b00405
Arora P., Zhang Z. // Chem. Rev. 2004. V. 104. № 10. P. 4419−4462. https://doi.org/10.1021/cr020738u
Elyashevich G., Karpov E., Kozlov A. // Macromol. Symp. 1999. V. 147. № 1. P. 91−101. https://doi.org/10.1002/masy.19991470110
Xie J., Xu R., Lei C. // Polymer. 2018. V. 158. № 5. P. 10−17. https://doi.org/10.1016/j.polymer.2018.10.047
Stribeck N., Zeinolebadi A., Fakirov S., Bhattacharyya D., Botta S. // Sci. Technol. Adv. Mater. 2013. V. 14. № 3. P. 035006. https://doi.org/10.1088/1468-6996/14/3/035006
Arzhakova O.V., Nazarov A.I., Solovei A.R., Dolgova A.A., Kopnov A.Yu., Chaplygin D.K., Tyubaeva P.M., Yarysheva A.Yu. // Membranes. 2021. V. 11. P. 834−852. https://doi.org/10.3390/membranes11110834
Arzhakova O.V., Kovalenko S.M., Kopnov A.Yu., Naza-rov A.I., Kopnova T.Yu., Shpolvind N.A., Tyubaeva P.M., Cherdyntseva T.A., Yarysheva A.Yu., Dolgova A.A., Volynskii A.L. // Rus. J. Gen. Chem. 2021. V. 91. № 11. P. 2249–2256. https://doi.org/10.1134/S1070363221110104
Arzhakova O.V., Kopnov A.Yu., Nazarov A.I., Dolgova A.A., Volynskii A.L. // Polymer. 2020. V. 186. 122020. https://doi.org/10.1016/j.polymer.2019.122020
Volynskii A.L., Bakeev N.F. Surface phenomena in the structural and mechanical behaviour of solid polymers. London, New York: Taylor & Francis, 2016. 526 p.
Arzhakova O.V., Dolgova A.A., Yarysheva A.Yu., Nikishin I.I., Volynskii A.L. // ACS Appl. Polym. Mater. 2020. V. 2. № 6. P. 2338–2349. https://doi.org/0.1021/acsapm.0c00288
Deblieck R.A.S., van Beek D.J.M., Remerie K., Ward M.I. // Polymer. 2011. V. 52. № 4. P. 2979−2990. https://doi.org/10.1016/j.polymer.2011.03.055
Yarysheva A.Yu., Bagrov D.V., Kechek’yan P.A., Rukh-lya E.G., Bakirov A.V., Yarysheva L.M., Chvalun S.N., Volynskii A.L. // Polymer. 2019. V. 169. P. 234−242. https://doi.org/10.1016/j.polymer.2019.02.066
Roenko A.O., Trofimchuk E.S., Efimov A.V., Armeev G.A., Nikonorova N.I., Nikolaev A.Yu., Volynskii A.L. // Polym. Sci., Ser. A. 2021. V. 63. № 5. P. 471–484. https://doi.org/10.1134/S0965545X21050126
Racherla V., Lopez-Pamies O., Castaneda P.P. // Mech. Mater. 2010. V. 42. № 4. P. 451−468. https://doi.org/10.1016/j.mechmat.2009.11.005
Arzhakova O.V., Dolgova A.A., Rukhlya E.G., Volyn-skii A.L. // Polymer. 2019. V. 161. P. 151–161. https://doi.org/10.1016/j.polymer.2018.12.018