SYNTHESIS OF ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE WITH HIGH MELTING POINT IN OCTAFLUOROBUTANE MEDIUM

N. A. Rasputin; Распутин Н. А.; I. A. Vlasov; Власов И. А.; S. V. Yakovlev; Яковлев С. В.; G. A. Artem’ev; Артемьев Г. А.; I. L. Nikonov; Никонов И. Л.; D. S. Kopchuk; Копчук Д. С.; A. I. Matern; Матерн А. И.; V. N. Charushin; Чарушин В. Н.

doi:10.31857/S2686953522600350

SYNTHESIS OF ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE WITH HIGH MELTING POINT IN OCTAFLUOROBUTANE MEDIUM

Authors: Rasputin N.A.¹, Vlasov I.A.¹, Yakovlev S.V.¹, Artem’ev G.A.¹^,2, Nikonov I.L.¹^,2, Kopchuk D.S.¹^,2, Matern A.I.², Charushin V.N.¹^,2
Affiliations:
1. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
2. Yeltsin Ural Federal University
Issue: Vol 508, No 1 (2023)
Pages: 64-69
Section: CHEMICAL TECHNOLOGY
URL: https://rjmseer.com/2686-9535/article/view/651995
DOI: https://doi.org/10.31857/S2686953522600350
EDN: https://elibrary.ru/EVVTYW
ID: 651995

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Abstract

Ultra-high molecular weight polyethylene (UHMWPE) with a high melting point (T_m) up to 144°C was successfully obtained by suspension polymerization in 1,4-H-octafluorobutane medium initiated by Ziegler–Natta catalysts. This method makes it possible successfully to carry out polymerization at a temperature close to ambient one and an ethylene pressure close to atmospheric one. The resulting polyethylenes were characterized by IR spectroscopy, elemental analysis and derivatographic studies. Values of melting points and degrees of crystallinity of the synthesized polymers were obtained using these data.

Keywords

ultra-high molecular weight polyethylene (UHMWPE), suspension polymerization, fluorinated medium, 1,4H-octafluorobutane, derivatographic studies

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