Structural Diversity and Luminescent Properties of Lanthanide Coordination Polymers with 4,7-Di(4-Carboxypyrazole-1-Yl)-2,1,3-Benzoxadiazole

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Abstract

A series of new lanthanide metal-organic coordination polymers with 4,7-di(4-carboxypyrazol-1-yl)-2,1,3-benz- oxadiazole were synthesized. It was established that, depending on the position of element in the lanthanide series, products of four structural types are formed. In the case of the Ce3+ cation, the coordination polymer represents 1D chains, for Pr3+–Er3+ cations it is a 2D layered structure with layer concatenation, and for the late lanthanides Tm3+–Lu3+ two types of layered coordination polymers were identified, differing in the carboxylate group coordination mode and the number of coordinated water molecules in the coordination sphere of the central ion. The coordination polymers of Sm3+, Eu3+, Gd3+, and Tb3+ exhibit only ligand-centered luminescence with a maximum in the range of 540–550 nm, while the luminescence spectrum of Nd3+ coordination polymer additionally contains characteristic bands of metal-centered emission in the near infrared range at 878, 1054, 1330, and 1568 nm.

About the authors

E. R. Dudko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

D. I. Pavlov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

A. A. Ryadun

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

Yu. A. Kenzhebayeva

ITMO University

197101 St. Petersburg, Russian Federation

D. G. Samsonenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

V. A. Milichko

ITMO University

197101 St. Petersburg, Russian Federation

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

A. S. Potapov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: potapov@niic.nsc.ru
630090 Novosibirsk, Russian Federation

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