Email this article Photooxidation of bis-thiacarbocyanine dyes and their supramolecular complexes with cucurbit[8]uril by viologens
- Authors: Chibisov A.K.1, Zakharova G.V.1, Fedotova T.V.1
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Affiliations:
- Kurchatov Institute National Research Center, Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department
- Issue: Vol 522, No 1 (2025)
- Pages: 29-34
- Section: PHYSICAL CHEMISTRY
- URL: https://rjmseer.com/2686-9535/article/view/695879
- DOI: https://doi.org/10.31857/S2686953525030048
- ID: 695879
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Abstract
The photooxidation reaction of bis-thiacarbocyanines based on 3,3'-dimethylthiacarbocyanine by viologens (methyl viologen, p-chlorophenyl viologen, p-cyanophenyl viologen) in acetonitrile, as well as their complexes with cucurbit[8]uril by monomeric complexes of viologens with cucurbit[8]uril in water was studied. The result of the photooxidation reaction of dye monomers in acetonitrile is the formation of the thiacarbocyanine dication-radical, bis-thiacarbocyanine trication-radicals and viologen cation-radicals. The consequence of photooxidation in water in the presence of cucurbit[8]uril is the formation of trication radicals of dye complexes and cation radicals of viologen complexes.
About the authors
A. K. Chibisov
Kurchatov Institute National Research Center, Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department119421 Moscow, Russian Federation
G. V. Zakharova
Kurchatov Institute National Research Center, Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department
Email: gvzakharova@gmail.com
119421 Moscow, Russian Federation
T. V. Fedotova
Kurchatov Institute National Research Center, Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department119421 Moscow, Russian Federation
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