Magnetosensitive luminescence of recombination exciplexes of dimethyl and dimethoxy tolan with N,N-dimethylaniline generated by X-irradiation in nonpolar solution

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Abstract

On the example of three compounds it is demonstrated that upon X-irradiation in nonpolar solution donor- substituted dimethyl- and dimethoxy-(diphenylacetylenes) form exciplexes with N,N-dimethylaniline via recombination of the respective radical ions with an intense magnetosensitive band of luminescence. Exciplexes of dimethyldiphenylacetylenes have the highest light production of all recombination exciplexes of diphenylacetylenes known so far. The studied compounds and their analogs as a class may be considered as potential blue emitters for organic electroluminescent systems, including magnetosensitive ones.

About the authors

D. V. Stass

V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: stass@kinetics.nsc.ru
630090 Novosibirsk, Russian Federation; 630090 Novosibirsk, Russian Federation

V. N. Verkhovlyuk

HUN-REN Wigner Research Centre for Physics

P.O. Box 49, H-1525 Budapest, Hungary

A. A. Stepanov

V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

S. F. Vasilevsky

V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences

630090 Novosibirsk, Russian Federation

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